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Use of Photoacoustic Excitation and Laser Vibrometry to Remotely Detect Trace Explosives

Summary

In this paper, we examine a laser-based approach to remotely initiate, measure, and differentiate acoustic and vibrational emissions from trace quantities of explosive materials against their environment. Using a pulsed ultraviolet laser (266 nm), we induce a significant (>100  Pa) photoacoustic response from small quantities of military-grade explosives. The photoacoustic signal, with frequencies predominantly between 100 and 500 kHz, is detected remotely via a wideband laser Doppler vibrometer. This two-laser system can be used to rapidly detect and discriminate explosives from ordinary background materials, which have significantly weaker photoacoustic response. A 100  ng/cm2 limit of detection is estimated. Photoablation is proposed as the dominant mechanism for the large photoacoustic signals generated by explosives.
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Summary

In this paper, we examine a laser-based approach to remotely initiate, measure, and differentiate acoustic and vibrational emissions from trace quantities of explosive materials against their environment. Using a pulsed ultraviolet laser (266 nm), we induce a significant (>100  Pa) photoacoustic response from small quantities of military-grade explosives. The photoacoustic signal...

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Trace aerosol detection and identification by dynamic photoacoustic spectroscopy

Published in:
Opt. Express, Vol. 22, No. 25, 15 December 2014, pp. A1810-A1817.

Summary

Dynamic photoacoustic spectroscopy (DPAS) is a high sensitivity technique for standoff detection of trace vapors. A field-portable DPAS system has potential as an early warning provider for gaseous-based chemical threats. For the first time, we utilize DPAS to successfully detect the presence of trace aerosols. Aerosol identification via long-wavelength infrared (LWIR) spectra is demonstrated. We estimate the sensitivity of our DPAS system to aerosols comprised of silica particles is comparable to that of SF6 gas based on a signal level per absorbance unit metric for the two materials. The implications of the measurements are discussed.
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Summary

Dynamic photoacoustic spectroscopy (DPAS) is a high sensitivity technique for standoff detection of trace vapors. A field-portable DPAS system has potential as an early warning provider for gaseous-based chemical threats. For the first time, we utilize DPAS to successfully detect the presence of trace aerosols. Aerosol identification via long-wavelength infrared...

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High-sensitivity detection of trace gases using dynamic photoacoustic spectroscopy

Published in:
Opt. Eng., Vol. 53 No. 2, February 2014, 021103.

Summary

Lincoln Laboratory of Massachusetts Institute of Technology has developed a technique known as dynamic photoacoustic spectroscopy (DPAS) that could enable remote detection of trace gases via a field-portable laser-based system. A fielded DPAS system has the potential to enable rapid, early warning of airborne chemical threats. DPAS is a new form of photoacoustic spectroscopy that relies on a laser beam swept at the speed of sound to amplify an otherwise weak photoacoustic signal. We experimentally determine the sensitivity of this technique using trace quantities of SF6 gas. A clutter-limited sensitivity of ~100 ppt is estimated for an integration path of 0.43 m. Additionally, detection at ranges over 5 m using two different detection modalities is demonstrated: a parabolic microphone and a laser vibrometer. Its utility in detecting ammonia emanating from solid samples in an ambient environment is also demonstrated.
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Summary

Lincoln Laboratory of Massachusetts Institute of Technology has developed a technique known as dynamic photoacoustic spectroscopy (DPAS) that could enable remote detection of trace gases via a field-portable laser-based system. A fielded DPAS system has the potential to enable rapid, early warning of airborne chemical threats. DPAS is a new...

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Dynamic photoacoustic spectroscopy for trace gas detection

Published in:
Appl. Phys. Lett., Vol. 101, No. 18, 29 October 2012, 184103.

Summary

We present a method of photoacoustic spectroscopy in which a laser beam tuned to an absorption feature of a gas is swept through its plume at the speed of sound. The resulting coherent addition of acoustic waves leads to an amplification of the signal without the need for a resonant chamber, thus enhancing the ability to remotely sense the gas. We demonstrate the concept using a tunable CO2 laser and SF6 gas in conjunction with a microphone. Sound pressure levels of 83 dB (relative to 20 uPa) are generated from a 15-ppm plume.
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Summary

We present a method of photoacoustic spectroscopy in which a laser beam tuned to an absorption feature of a gas is swept through its plume at the speed of sound. The resulting coherent addition of acoustic waves leads to an amplification of the signal without the need for a resonant...

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Noncontact optical detection of explosive particles via photodissociation followed by laser-induced fluorescence

Published in:
Opt. Express, Vol. 19, No. 19, 12 September 2011, pp. 18671-18677.

Summary

High-sensitivity (ng/cm2) optical detection of the explosive 2,4,6- trinitrotoluene (TNT) is demonstrated using photodissociation followed by laser-induced fluorescence (PD-LIF). Detection occurs rapidly, within 6 laser pulses (~7 ns each) at a range of 15 cm. Dropcasting is used to create calibrated samples covering a wide range of TNT concentrations; and a correspondence between fractional area covered by TNT and PD-LIF signal strength is observed. Dropcast data are compared to that of an actual fingerprint. These results demonstrate that PD-LIF could be a viable means of rapidly and remotely scanning surfaces for trace explosive residues.
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Summary

High-sensitivity (ng/cm2) optical detection of the explosive 2,4,6- trinitrotoluene (TNT) is demonstrated using photodissociation followed by laser-induced fluorescence (PD-LIF). Detection occurs rapidly, within 6 laser pulses (~7 ns each) at a range of 15 cm. Dropcasting is used to create calibrated samples covering a wide range of TNT concentrations; and...

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Noncontact detection of homemade explosive constituents via photodissociation followed by laser-induced fluorescence

Published in:
Opt. Express, Vol. 18, No. 6, 15 March 2010, pp. 5399-5406.

Summary

Noncontact detection of the homemade explosive constituents urea nitrate, nitromethane and ammonium nitrate is achieved using photodissociation followed by laser-induced fluorescence (PD-LIF). Our technique utilizes a single ultraviolet laser pulse (~7 ns) to vaporize and photodissociate the condensed-phase materials, and then to detect the resulting vibrationally-excited NO fragments via laser-induced fluorescence. PD-LIF excitation and emission spectra indicate the creation of NO in vibrationally-excited states with significant rotational energy, useful for low-background detection of the parent compound. The results for homemade explosives are compared to one another and 2,6- dinitrotoluene, a component present in many military explosives.
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Summary

Noncontact detection of the homemade explosive constituents urea nitrate, nitromethane and ammonium nitrate is achieved using photodissociation followed by laser-induced fluorescence (PD-LIF). Our technique utilizes a single ultraviolet laser pulse (~7 ns) to vaporize and photodissociate the condensed-phase materials, and then to detect the resulting vibrationally-excited NO fragments via laser-induced...

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A novel method for remotely detecting trace explosives

Published in:
Lincoln Laboratory Journal, Vol. 17, No. 2, December 2008, pp. 27-40.

Summary

The development of a technique with the ability to detect trace quantities of explosives at a distance is of critical importance. In numerous situations when explosive devices are prepared, transported, or otherwise handled, quantifiable amounts of the explosive material end up on surfaces. Rapid detection of these chemical residues in a noninvasive standoff manner would serve as an indicator for attempts at concealed assembly or transport of explosive materials and devices. We are investigating the use of a fluorescence-based technique to achieve the necessary detection sensitivity.
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Summary

The development of a technique with the ability to detect trace quantities of explosives at a distance is of critical importance. In numerous situations when explosive devices are prepared, transported, or otherwise handled, quantifiable amounts of the explosive material end up on surfaces. Rapid detection of these chemical residues in...

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Detection of condensed-phase explosives via laser-induced vaporization, photodissociation, and resonant excitation

Published in:
Appl. Opt., Vol. 47, No. 31, 1 November 2008, pp. 5767-5776.

Summary

We investigate the remote detection of explosives via a technique that vaporizes and photodissociates the condensed-phase material and detects the resulting vibrationally excited NO fragments via laser-induced fluorescence. The technique utilizes a single 7 ns pulse of a tunable laser near 236:2nm to perform these multiple processes. The resulting blue-shifted fluorescence (226 nm) is detected using a photomultiplier and narrowband filter that strongly block the scatter of the pump laser off the solid media while passing the shorter wavelength photons. Various nitro-bearing compounds, including 2,6-dinitrotoluene (DNT), 2,4,6-trinitrotoluene (TNT), pentaerythritol tetranitrate (PETN), and hexahydro-1,3,5- trinitro-1,3,5-triazine (RDX) were detected with a signal-to-noise of 25 dB. The effects of laser fluence, wavelength, and sample morphology were examined.
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Summary

We investigate the remote detection of explosives via a technique that vaporizes and photodissociates the condensed-phase material and detects the resulting vibrationally excited NO fragments via laser-induced fluorescence. The technique utilizes a single 7 ns pulse of a tunable laser near 236:2nm to perform these multiple processes. The resulting blue-shifted...

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Experimental demonstration of remote optical detection of trace explosives.

Published in:
SPIE Vol. 6954, Chemical, Biologica, Radiological, Nuclear and Explosives (CBRNE) Sensing IX, 18-20 March 2008, 695407.

Summary

MIT Lincoln Laboratory has developed a concept that could enable remote (10s of meters) detection of trace explosives' residues via a field-portable laser system. The technique relies upon laser-induced photodissociation of nitro-bearing explosives into vibrationally excited nitric oxide (NO) fragments. Subsequent optical probing of the first vibrationally excited state at 236 nm yields narrowband fluorescence at the shorter wavelength of 226 nm. With proper optical filtering, these photons provide a highly sensitive explosives signature that is not susceptible to interference from traditional optical clutter sources (e.g., red-shifted fluorescence). Quantitative measurements of trace residues of TNT have been performed demonstrating this technique using a breadboard system, which relies upon a pulsed optical parametric oscillator (OPO) based laser. Based on these results, performance projections for a fieldable system are made.
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Summary

MIT Lincoln Laboratory has developed a concept that could enable remote (10s of meters) detection of trace explosives' residues via a field-portable laser system. The technique relies upon laser-induced photodissociation of nitro-bearing explosives into vibrationally excited nitric oxide (NO) fragments. Subsequent optical probing of the first vibrationally excited state at...

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Integration of high-speed surface-channel charge coupled devices into an SOI CMOS process using strong phase shift lithography

Published in:
SPIE Vol. 6924, Optical Microlithography XXI, 26-27 February 2008, pp. 69244R.

Summary

To enable development of novel signal processing circuits, a high-speed surface-channel charge coupled device (CCD) process has been co-integrated with the Lincoln Laboratory 180-nm RF fully depleted silicon-on-insulator (FDSOI) CMOS technology. The CCDs support charge transfer clock speeds in excess of 1 GHz while maintaining high charge transfer efficiency (CTE). Both the CCD and CMOS gates are formed using a single-poly process, with CCD gates isolated by a narrow phase-shift-defined gap. CTE is strongly dependent on tight control of the gap critical dimension (CD). In this paper we review the tradeoffs encountered in the co-integration of the CCD and CMOS technologies. The effect of partial coherence on gap resolution and pattern fidelity is discussed. The impact of asymmetric bias due to phase error and phase shift mask (PSM) sidewall effects is presented, along with adopted mitigation strategies. Issues relating to CMOS pattern fidelity and CD control in the double patterning process are also discussed. Since some signal processing CCD structures involve two-dimensional transfer paths, many required geometries present phase compliance and trim engineering challenges. Approaches for implementing noncompliant geometries, such as T shapes, are described, and the impact of various techniques on electrical performance is discussed.
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Summary

To enable development of novel signal processing circuits, a high-speed surface-channel charge coupled device (CCD) process has been co-integrated with the Lincoln Laboratory 180-nm RF fully depleted silicon-on-insulator (FDSOI) CMOS technology. The CCDs support charge transfer clock speeds in excess of 1 GHz while maintaining high charge transfer efficiency (CTE)...

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