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Engineered liquid crystal anchoring energies with nanopatterned surfaces

Published in:
Opt. Express, Vol. 23, No. 2, 26 January 2015, pp. 807-14.

Summary

The anchoring energy of liquid crystals was shown to be tunable by surface nanopatterning of periodic lines and spaces. Both the pitch and height were varied using hydrogen silsesquioxane negative tone electron beam resist, providing for flexibility in magnitude and spatial distribution of the anchoring energy. Using twisted nematic liquid crystal cells, it was shown that this energy is tunable over an order of magnitude. These results agree with a literature model which predicts the anchoring energy of sinusoidal grooves.
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Summary

The anchoring energy of liquid crystals was shown to be tunable by surface nanopatterning of periodic lines and spaces. Both the pitch and height were varied using hydrogen silsesquioxane negative tone electron beam resist, providing for flexibility in magnitude and spatial distribution of the anchoring energy. Using twisted nematic liquid...

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Trace aerosol detection and identification by dynamic photoacoustic spectroscopy

Published in:
Opt. Express, Vol. 22, No. 25, 15 December 2014, pp. A1810-A1817.

Summary

Dynamic photoacoustic spectroscopy (DPAS) is a high sensitivity technique for standoff detection of trace vapors. A field-portable DPAS system has potential as an early warning provider for gaseous-based chemical threats. For the first time, we utilize DPAS to successfully detect the presence of trace aerosols. Aerosol identification via long-wavelength infrared (LWIR) spectra is demonstrated. We estimate the sensitivity of our DPAS system to aerosols comprised of silica particles is comparable to that of SF6 gas based on a signal level per absorbance unit metric for the two materials. The implications of the measurements are discussed.
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Summary

Dynamic photoacoustic spectroscopy (DPAS) is a high sensitivity technique for standoff detection of trace vapors. A field-portable DPAS system has potential as an early warning provider for gaseous-based chemical threats. For the first time, we utilize DPAS to successfully detect the presence of trace aerosols. Aerosol identification via long-wavelength infrared...

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Liquid crystal uncooled thermal imager development

Published in:
2014 Military Sensing Symposia, (MSS 2014), Detectors and Materials, 9 September 2014.

Summary

An uncooled thermal imager is being developed based on a liquid crystal transducer. The liquid crystal transducer changes a long-wavelength infrared scene into a visible image as opposed to an electric signal in microbolometers. This approach has the potential for making a more flexible thermal sensor. One objective is to develop imager technology scalable to large formats (tens of megapixels) while maintaining or improving the noise equivalent temperature difference (NETD) compared to microbolometers. Our work is demonstrating that the liquid crystals have the required performance (sensitivity, dynamic range, speed, etc.) to make state-of-the-art uncooled imagers. A process has been developed and arrays have been fabricated using the liquid crystals. A breadboard camera system has been assembled to test the imagers. Results of the measurements are discussed.
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Summary

An uncooled thermal imager is being developed based on a liquid crystal transducer. The liquid crystal transducer changes a long-wavelength infrared scene into a visible image as opposed to an electric signal in microbolometers. This approach has the potential for making a more flexible thermal sensor. One objective is to...

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Chemical aerosol detection and identification using Raman scattering

Published in:
J. Raman Spectrosc., Vol. 45, No. 8, August 2014, pp. 677-9.

Summary

Early warning of the presence of chemical agent aerosols is an important component in the defense against such agents. A Raman spectrometer has been constructed for the purpose of detecting and identifying chemical aerosols. We report the detection and identification of a low-concentration chemical aerosol in atmospheric air using 532-nm continuous wave laser Raman scattering. We have demonstrated the Raman scattering detection and identification of an aerosol of isovanillin of mass concentration of 1.8 ng/cm^3 with a signal-to-noise ratio of about 19 in 30 s for the 116-cm^-1 mode with a Raman cross section of 3.3 x 10^-28 cm^2 using 8-W double-pass laser power.
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Summary

Early warning of the presence of chemical agent aerosols is an important component in the defense against such agents. A Raman spectrometer has been constructed for the purpose of detecting and identifying chemical aerosols. We report the detection and identification of a low-concentration chemical aerosol in atmospheric air using 532-nm...

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Impact ionization in AlxGa1-xASySb1-y avalanche photodiodes

Summary

Avalanche photodiodes (APDs) have been fabricated in order to determine the impact ionization coefficients of electrons (alpha) and holes (beta) in AlxGa1-xAsySb1-y lattice matched to GaSb for three alloy compositions: (x=0.40, y=0.035), (x=0.55, y=0.045), and (x=0.65, y=0.054). The impact ionization coefficients were calculated from photomultiplication measurements made on specially designed APDs, which allowed for both pure electron and pure hole injection in the same device. Photo-multiplication measurements were made at temperatures ranging from 77K to 300K for all three alloys. A quasi-physical model with an explicit temperature dependence was used to express the impact ionization coefficients as a function of electric-field strength and temperature. For all three alloys, it was found that alpha < beta at any given temperature. In addition, the values of the impact ionization coefficients were found to decrease as the aluminum concentration of the AlGaAsSb alloy was increased. A value between 1.2 and 4.0 was found for beta/x, which is dependent on temperature, alloy composition, and electric-field strength.
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Summary

Avalanche photodiodes (APDs) have been fabricated in order to determine the impact ionization coefficients of electrons (alpha) and holes (beta) in AlxGa1-xAsySb1-y lattice matched to GaSb for three alloy compositions: (x=0.40, y=0.035), (x=0.55, y=0.045), and (x=0.65, y=0.054). The impact ionization coefficients were calculated from photomultiplication measurements made on specially designed...

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High-sensitivity detection of trace gases using dynamic photoacoustic spectroscopy

Published in:
Opt. Eng., Vol. 53 No. 2, February 2014, 021103.

Summary

Lincoln Laboratory of Massachusetts Institute of Technology has developed a technique known as dynamic photoacoustic spectroscopy (DPAS) that could enable remote detection of trace gases via a field-portable laser-based system. A fielded DPAS system has the potential to enable rapid, early warning of airborne chemical threats. DPAS is a new form of photoacoustic spectroscopy that relies on a laser beam swept at the speed of sound to amplify an otherwise weak photoacoustic signal. We experimentally determine the sensitivity of this technique using trace quantities of SF6 gas. A clutter-limited sensitivity of ~100 ppt is estimated for an integration path of 0.43 m. Additionally, detection at ranges over 5 m using two different detection modalities is demonstrated: a parabolic microphone and a laser vibrometer. Its utility in detecting ammonia emanating from solid samples in an ambient environment is also demonstrated.
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Summary

Lincoln Laboratory of Massachusetts Institute of Technology has developed a technique known as dynamic photoacoustic spectroscopy (DPAS) that could enable remote detection of trace gases via a field-portable laser-based system. A fielded DPAS system has the potential to enable rapid, early warning of airborne chemical threats. DPAS is a new...

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Reagent assessment for detection of ammonium ion-molecule complexes

Published in:
Rapid Commun. Mass Spectrom., Vol. 27, 2013, pp. 2797-2806.

Summary

An MS-based framework was developed to quantitatively assess API ion-molecule reagent chemistries based on ammonium selectivity versus competing ions, and intrinsic ammonium binding strength and complex survivability for detection. Methyl acetoacetate is an attractive ammonium reagent for vapor-phase API techniques given its high vapor pressure, preferential selectivity, and high critical energy for dissociation.
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Summary

An MS-based framework was developed to quantitatively assess API ion-molecule reagent chemistries based on ammonium selectivity versus competing ions, and intrinsic ammonium binding strength and complex survivability for detection. Methyl acetoacetate is an attractive ammonium reagent for vapor-phase API techniques given its high vapor pressure, preferential selectivity, and high critical...

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Pixel-processing imager development for directed energy applications

Summary

Tactical high-energy laser (HEL) systems face a range of imaging-related challenges in wavefront sensing, acquiring and tracking targets, selecting the HEL aimpoint, and assessing lethality. Accomplishing these functions in a timely fashion may be limited by competing requirements on total field of regard, target resolution, signal to noise, and focal plane readout bandwidth. In this paper, we explore the applicability of an emerging pixel-processing imager (PPI) technology to these challenges. The on-focal-plane signal processing capabilities of the MIT Lincoln Laboratory PPI technology have recently been extended in support of directed energy applications. We describe this work as well as early results from a new PPI-based short-wave-infrared focal plane readout capable of supporting diverse applications such as low-latency Shack-Hartmann wavefront sensing, centroid computation, and Fitts correlation tracking.
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Summary

Tactical high-energy laser (HEL) systems face a range of imaging-related challenges in wavefront sensing, acquiring and tracking targets, selecting the HEL aimpoint, and assessing lethality. Accomplishing these functions in a timely fashion may be limited by competing requirements on total field of regard, target resolution, signal to noise, and focal...

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Etching selectivity of indium tin oxide to photoresist in high density chlorine- and ethylene-containing plasmas

Author:
Published in:
J. Vac. Sci. Technol. B, Microelectron. and Nanometer Structures, Vol. 31, No. 2, 13 March 2013, 021210.

Summary

Etching of indium tin oxide (ITO) thin films in high density chlorine plasmas is studied, with the goal of increasing the etching selectivity to photoresist. The ITO etching rate increases with ethylene addition, but is not affected by BCl3 addition. ITO exhibits a threshold energy for ion etching, whereas the photoresist etches spontaneously in chlorine plasmas. The ITO:photoresist selectivity increases with BCl3 addition, ion bombardment energy, and C2H4 addition. It is proposed that the ITO etching rate is limited by desorption of InClx products, and that ethylene addition assists in scavenging oxygen from ITO leaving loosely bound In, which is more easily removed by physical sputtering.
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Summary

Etching of indium tin oxide (ITO) thin films in high density chlorine plasmas is studied, with the goal of increasing the etching selectivity to photoresist. The ITO etching rate increases with ethylene addition, but is not affected by BCl3 addition. ITO exhibits a threshold energy for ion etching, whereas the...

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Nonlinear bleaching, absorption, and scattering of 532-nm-irradiated plasmonic nanoparticles

Published in:
J. Appl. Phys., Vol. 113. No. 5, 7 February 2013, 053107.

Summary

Single-pulse irradiation of Au and Ag suspensions of nanospheres and nanodisks with 532-nm 4-ns pulses has identified complex optical nonlinearities while minimizing material damage. For all materials tested, we observe competition between saturable absorption (SA) and reverse SA (RSA), with RSA behavior dominating for intensities above ~50 MW/cm^2. Due to reduced laser damage in single-pulse experiments, the observed intrinsic nonlinear absorption coefficients are the highest reported to date for Au nanoparticles. We find size dependence to the nonlinear absorption enhancement for Au nanoparticles, peaking in magnitude for 80-nm nanospheres and falling off at larger sizes. The nonlinear absorption coefficients for Au and Ag spheres are comparable in magnitude. On the other hand, the nonlinear absorption for Ag disks, when corrected for volume fraction, is several times higher. These trends in nonlinear absorption are correlated to local electric field enhancement through quasi-static mean-field theory. Through variable size aperture measurements, we also separate nonlinear scattering from nonlinear absorption. For all materials tested, we find that nonlinear scattering is highly directional and that its magnitude is comparable to that of nonlinear absorption. These results indicate methods to improve the efficacy of plasmonic nanoparticles as optical limiters in pulsed laser systems.
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Summary

Single-pulse irradiation of Au and Ag suspensions of nanospheres and nanodisks with 532-nm 4-ns pulses has identified complex optical nonlinearities while minimizing material damage. For all materials tested, we observe competition between saturable absorption (SA) and reverse SA (RSA), with RSA behavior dominating for intensities above ~50 MW/cm^2. Due to...

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