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Etching selectivity of indium tin oxide to photoresist in high density chlorine- and ethylene-containing plasmas

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Published in:
J. Vac. Sci. Technol. B, Microelectron. and Nanometer Structures, Vol. 31, No. 2, 13 March 2013, 021210.

Summary

Etching of indium tin oxide (ITO) thin films in high density chlorine plasmas is studied, with the goal of increasing the etching selectivity to photoresist. The ITO etching rate increases with ethylene addition, but is not affected by BCl3 addition. ITO exhibits a threshold energy for ion etching, whereas the photoresist etches spontaneously in chlorine plasmas. The ITO:photoresist selectivity increases with BCl3 addition, ion bombardment energy, and C2H4 addition. It is proposed that the ITO etching rate is limited by desorption of InClx products, and that ethylene addition assists in scavenging oxygen from ITO leaving loosely bound In, which is more easily removed by physical sputtering.
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Summary

Etching of indium tin oxide (ITO) thin films in high density chlorine plasmas is studied, with the goal of increasing the etching selectivity to photoresist. The ITO etching rate increases with ethylene addition, but is not affected by BCl3 addition. ITO exhibits a threshold energy for ion etching, whereas the...

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Development of adaptive liquid microlenses and microlens arrays

Published in:
SPIE Photonics West 2013: MOEMS-MEMS, 2-7 February 2013.

Summary

We report on the development of sub-millimeter size adaptive liquid microlenses and microlens arrays using two immiscible liquids to form individual lenses. Microlenses and microlens arrays having aperture diameters as small as 50 microns were fabricated on a planar quartz substrate using patterned hydrophobic/hydrophilic regions. Liquid lenses were formed by a self-assembled oil dosing process that created well-defined lenses having a high fill factor. Variable focus was achieved by controlling the lens curvature through electrowetting. Greater than 70 degrees of contact angle change was achieved with less than 20 volts, which results in a large optical power dynamic range.
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Summary

We report on the development of sub-millimeter size adaptive liquid microlenses and microlens arrays using two immiscible liquids to form individual lenses. Microlenses and microlens arrays having aperture diameters as small as 50 microns were fabricated on a planar quartz substrate using patterned hydrophobic/hydrophilic regions. Liquid lenses were formed by...

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Switchable electrowetting of droplets on dual-scale structured surfaces

Published in:
J. Vac. Sci. Technol. B, Microelectron. Process. Phenon., Vol. 30, No. 6, November 2012, 06F801.

Summary

The authors report on the development of surfaces containing artificially fabricated structures of dual nanometer and micrometer surfaces that allow an aqueous droplet to be reversibly switched by electrowetting from a Cassie state with low adhesion to a Wenzel state with high adhesion. A variety of geometries were fabricated to study parameters that affect switchable wetting-dewetting. Nanometer parallel corrugations, posts, and holes were fabricated and combined with micrometer features consisting of parallel corrugations, streets, and checkerboard patterns of varying widths and pitches. It was observed that many combinations of the dual-textured surfaces produced superhydrophobic wetting states and aqueous droplets on these surfaces could be electrically controlled to switch from a Cassie state to a Wenzel state. Reversible switching between these wetting states occurred on specific combinations of surface geometries, namely surfaces that had parallel corrugations.
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Summary

The authors report on the development of surfaces containing artificially fabricated structures of dual nanometer and micrometer surfaces that allow an aqueous droplet to be reversibly switched by electrowetting from a Cassie state with low adhesion to a Wenzel state with high adhesion. A variety of geometries were fabricated to...

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Reversible electrowetting on dual-scale-patterned corrugated microstructured surfaces

Published in:
J. of Microeletromechanical Systems, Vol. 21, No. 5, October 2012, pp. 1261-71.

Summary

The ability to reversibly switch between a hydrophobic Cassie state and a hydrophilic Wenzel state is often not possible on textured surfaces because of energy barriers which result from the geometry of the microstructure. In this paper, we report on a simple microstructure geometry that allows an aqueous droplet to be reversibly switched between these states by the application of electrowetting. We demonstrate reversible electrowetting in air on microstructured surfaces consisting of parallel corrugations and show that this geometry can be engineered to produce a Cassie state and can be electrically controlled to switch to a Wenzel wetting state having high adhesion. When the electric field was removed, we observed spontaneous dewetting along the corrugations as the droplet transitioned from the Wenzel state back to a Cassie state.
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Summary

The ability to reversibly switch between a hydrophobic Cassie state and a hydrophilic Wenzel state is often not possible on textured surfaces because of energy barriers which result from the geometry of the microstructure. In this paper, we report on a simple microstructure geometry that allows an aqueous droplet to...

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New generation of digital microfluidic devices

Published in:
J. Microelectromech. Syst., Vol. 18, No. 4, August 2009, pp. 845-851.

Summary

This paper reports on the design, fabrication, and performance of micro-sized fluidic devices that use electrowetting to control and transport liquids. Using standard microfabrication techniques, new pumping systems are developed with significantly more capability than open digital microfluidic systems that are often associated with electrowetting. This paper demonstrates that, by integrating closed microchannels with different channel heights and using electrowetting actuation, liquid interfaces can be controlled, and pressure work can be done, resulting in fluid pumping. The operation of two different on-chip pumps and devices that can form water drops is described. In addition, a theory is presented to explain the details of single-electrode actuation in a closed channel.
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Summary

This paper reports on the design, fabrication, and performance of micro-sized fluidic devices that use electrowetting to control and transport liquids. Using standard microfabrication techniques, new pumping systems are developed with significantly more capability than open digital microfluidic systems that are often associated with electrowetting. This paper demonstrates that, by...

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New methods to transport fluids in micro-sized devices

Published in:
Lincoln Laboratory Journal, Vol. 17, No. 2, December 2008, pp. 70-80.

Summary

Applications of microfluidics require a self-contained, active pumping system in which the package size is comparable to the volume of fluid being transported. Over the past decade, several systems have been developed to address this issue, but either these systems have high power requirements or the microfabrication is too complex to be cost efficient. A recent effort at Lincoln Laboratory using an emerging technology called electrowetting has led to the development of several novel micropump concepts for pumping liquids continuously, as well as for pumping discrete volumes.
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Summary

Applications of microfluidics require a self-contained, active pumping system in which the package size is comparable to the volume of fluid being transported. Over the past decade, several systems have been developed to address this issue, but either these systems have high power requirements or the microfabrication is too complex...

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Irreversible electrowetting on thin fluoropolymer films

Published in:
Langmuir, Vol. 23, No. 24, 20 November 2007, pp. 12429-12435.

Summary

A study was conducted to investigate electrowetting reversibility associated with repeated voltage actuations for an aqueous droplet situated on a silicon dioxide insulator coated with an amorphous fluoropolymer film ranging in thickness from 20 to 80 nm. The experimental results indicate that irreversible trapped charge may occur at the aqueous-solid interface, giving rise to contact angle relaxation. The accumulation of trapped charge was found to be related to the applied electric field intensity and the breakdown strength of the fluoropolymer. On the basis of the data, an empirical model was developed to estimate the amount of trapped charge in the fluoropolymer as well as the voltage threshold for the onset of irreversible electrowetting.
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Summary

A study was conducted to investigate electrowetting reversibility associated with repeated voltage actuations for an aqueous droplet situated on a silicon dioxide insulator coated with an amorphous fluoropolymer film ranging in thickness from 20 to 80 nm. The experimental results indicate that irreversible trapped charge may occur at the aqueous-solid...

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Laser-induced fluorescence-cued, laser induced- breakdown spectroscopy biological-agent detection

Published in:
Appl. Opt., Vol. 45, No. 34, 1 December 2006, pp. 8806-8814.

Summary

Methods for accurately characterizing aerosols are required for detecting biological warfare agents. Currently, fluorescence-based biological agent sensors provide adequate detection sensitivity but suffer from high false-alarm rates. Combining single-particle fluorescence analysis with laser-induced breakdown spectroscopy (LIBS) provides additional discrimination and potentially reduces false-alarm rates. A transportable UV laser-induced fluorescence-cued LIBS test bed has been developed and used to evaluate the utility of LIBS for biological-agent detection. Analysis of these data indicates that LIBS adds discrimination capability to fluorescence-based biological-agent detectors. However, the data also show that LIBS signatures of biological agent simulants are affected by washing. This may limit the specificity of LIBS and narrow the scope of its applicability in biological-agent detection.
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Summary

Methods for accurately characterizing aerosols are required for detecting biological warfare agents. Currently, fluorescence-based biological agent sensors provide adequate detection sensitivity but suffer from high false-alarm rates. Combining single-particle fluorescence analysis with laser-induced breakdown spectroscopy (LIBS) provides additional discrimination and potentially reduces false-alarm rates. A transportable UV laser-induced fluorescence-cued LIBS...

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Low voltage electrowetting using thin fluoroploymer films

Published in:
J. Colloid and Interface Sci., Vol. 303, No. 2, 15 November 2006, pp. 517-524.

Summary

This paper investigates the nonideal electrowetting behavior of thin fluoroploymer films. Results are presented for a three phase system consisting of: (1) an aqueous water droplet containing sodium dodecyl sulfate (SDS), (2) phosphorous-doped silicon topped with SiO2 and an amorphous fluoroploymer (aFP) insulating top layer on which the droplet is situated, and (3) a dodecane oil that surrounds the droplet. The presented measurements indicate that the electrowetting equation is valid down to a 6 nm thick aFP film on a 11 nm thick SiO2. At this dielectric thickness, a remarkable contact angle change of over 100degreescan be achieved with an applied voltage less than 3 V across the system. The data also shows that for this water/surfactant/oil system, contact angle saturation is independent of the electric field, and is reached when the surface energy of the solid-water interface approaches zero.
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Summary

This paper investigates the nonideal electrowetting behavior of thin fluoroploymer films. Results are presented for a three phase system consisting of: (1) an aqueous water droplet containing sodium dodecyl sulfate (SDS), (2) phosphorous-doped silicon topped with SiO2 and an amorphous fluoroploymer (aFP) insulating top layer on which the droplet is...

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Engineering of the electrocapillary behavior of electrolyte droplets on thin fluoropolymer films

Published in:
Langmuir, Vol. 22, No. 13, 20 June 2006, pp. 5690-5696.

Summary

This study presents methods for engineering the electrocapillary behavior of fluoropolymer surfaces through the use of surfactants and an external insulating liquid. By the scaling of the appropriate surface energies, electrocapillary behavior is obtained at a record low voltage, with contact angle changes in excess of 100[degrees] at 4 V. A consistent description of electrocapillary saturation is presented, identifying three separate regimes: breakdown, thermodynamic instability, and relaxation. Methods for identifying and mitigating some of the saturation behaviors are discussed. Finally, the parameters influencing the observed voltage of zero charge are summarized.
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Summary

This study presents methods for engineering the electrocapillary behavior of fluoropolymer surfaces through the use of surfactants and an external insulating liquid. By the scaling of the appropriate surface energies, electrocapillary behavior is obtained at a record low voltage, with contact angle changes in excess of 100[degrees] at 4 V...

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