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Raman Detection of a Single Airborne Aerosol Particles of Isovanillin(3.09 MB)

May 24, 2017
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Journal Article
Author:
Roshan L. Aggarwal
…
Published in:
AIP Advances, vol. 7, no. 5
Topic:
chemical technologies
R&D area:
R&D group:

Summary

Raman spectroscopy of trapped single aerosol particles has been reported previously. However, detection of single aerosol particles via Raman spectroscopy in a flowing system has not been yet reported. In this paper, we describe the first detection of single 3 um flowing airborne aerosol particles flowing through a Raman system, which is a simplified version of the previously reported system with a 532-nm, 10W cw double-pass laser, 532-nm isolator, and double-sided collection optics. The current system has single-pass laser, no 532-nm isolator, and single-sided collection optics. Previous Raman detection of single aerosol particles has been made using trapped particles.
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Summary

Raman spectroscopy of trapped single aerosol particles has been reported previously. However, detection of single aerosol particles via Raman spectroscopy in a flowing system has not been yet reported. In this paper, we describe the first detection of single 3 um flowing airborne aerosol particles flowing through a Raman system...

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Raman Detection of a Single Airborne Aerosol Particles of Isovanillin

Raman spectra and cross sections of ammonia, chlorine, hydrogen sulfide, phosgene, and sulfur dioxide toxic gases in the fingerprint region 400-1400 cm-1

February 11, 2016
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Journal Article
Author:
Roshan L. Aggarwal
…
Published in:
AIP Advances, Vol. 6, No. 2, February 2016, 025310, doi: 10.1063/1.4942109.
Topic:
chemical technologies
R&D area:
R&D group:

Summary

Raman spectra of ammonia (NH3), chlorine (Cl2), hydrogen sulfide (H2S), phosgene (COCl2), and sulfur dioxide (SO2) toxic gases have been measured in the fingerprint region 400-1400 cm-1. A relatively compact (< 2'x2'x2'), sensitive, 532 nm 10 W CW Raman system with double-pass laser and double-sided collection was used for these measurements. Two Raman modes are observed at 934 and 967 cm-1 in NH3. Three Raman modes are observed in Cl2 at 554, 547, and 539 cm-1, which are due to the 35/35 35/37, and 37/37 Cl isotopes, respectively. Raman modes are observed at 870, 570, and 1151 cm-1 in H2S, COCl2, and SO2, respectively. Values of 3.68 ± 0.26x10-32 cm2/sr (3.68 ± 0.26x10-36 m2/sr), 1.37 ± 0.10x10-30 cm2/sr (1.37 ± 0.10x10-34 m2/sr), 3.25 ± 0.23x10-31 cm2/sr (3.25 ± 0.23x10-35 m2/sr), 1.63 ± 0.14x10-30 cm2/sr (1.63 ± 0.14x10-34 m2/sr), and 3.08 ± 0.22x10-30 cm2/sr (and 3.08 ± 0.22x10-34 m2/sr) were determined for the differential Raman cross section of the 967 cm-1 mode of NH3, sum of the 554, 547, and 539 cm-1 modes of Cl2, 870 cm-1 mode of H2S, 570 cm-1 mode of COCl2, and 1151 cm-1 mode of SO2, respectively, using the differential Raman cross section of 3.56 ± 0.14x10-31 cm2/sr (3.56 ± 0.14x10-35 m2/sr) for the 1285 cm-1 mode of CO2 as the reference.
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Summary

Raman spectra of ammonia (NH3), chlorine (Cl2), hydrogen sulfide (H2S), phosgene (COCl2), and sulfur dioxide (SO2) toxic gases have been measured in the fingerprint region 400-1400 cm-1. A relatively compact ( 2'x2'x2'), sensitive, 532 nm 10 W CW Raman system with double-pass laser and double-sided collection was used for these...

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Raman spectra and cross sections of ammonia, chlorine, hydrogen sulfide, phosgene, and sulfur dioxide toxic gases in the fingerprint region 400-1400 cm-1

Photothermal speckle modulation for noncontact materials characterization

December 15, 2015
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Journal Article
Author:
Alexander M. Stolyarov
…
Published in:
Opt. Lett., Vol. 40, No. 24, 15 December 2015, pp. 5786-9.
Topic:
optics
R&D area:
R&D group:

Summary

We have developed a noncontact, photothermal materials characterization method based on visible-light speckle imaging. This technique is applied to remotely measure the infrared absorption spectra of materials and to discriminate materials based on their thermal conductivities. A wavelength-tunable (7.5-8.7 um), intensity-modulated, quantum cascade pump laser and a continuous-wave 532 nm probe laser illuminate a sample surface such that the two laser spots overlap. Surface absorption of the intensity-modulated pump laser induces a time-varying thermoelastic surface deformation, resulting in a time-varying 532 nm scattering speckle field from the surface. The speckle modulation amplitude, derived from a series of visible camera images, is found to correlate with the amplitude of the surface motion. By tuning the pump laser's wavelength over a molecular absorption feature, the amplitude spectrum of the speckle modulation is found to correlate to the IR absorption spectrum. As an example, we demonstrate this technique for spectroscopic identification of thin polymeric films. Furthermore, by adjusting the rate of modulation of the pump beam and measuring the associated modulation transfer to the visible speckle pattern, information about the thermal time constants of surface and sub-surface features can be revealed. Using this approach, we demonstrate the ability to distinguish between different materials (including metals, semiconductors, and insulators) based on differences in their thermal conductivities.
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Summary

We have developed a noncontact, photothermal materials characterization method based on visible-light speckle imaging. This technique is applied to remotely measure the infrared absorption spectra of materials and to discriminate materials based on their thermal conductivities. A wavelength-tunable (7.5-8.7 um), intensity-modulated, quantum cascade pump laser and a continuous-wave 532 nm...

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Photothermal speckle modulation for noncontact materials characterization

Sensitive detection and identification of isovanillin aerosol particles at the pg/cm^3 mass concentration level using Raman spectroscopy

June 8, 2015
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Journal Article
Author:
Roshan L. Aggarwal
…
Published in:
Aerosol Sci. Technol., Vol. 49, No. 9, 2015, pp. 753-6.
Topic:
detection systems
R&D area:
R&D group:

Summary

A compact Raman spectroscopy system with high sensitivity to chemical aerosols has been developed. This system has been used to detect isovanillin aerosols with mass concentration of 12 pg/cm3 in a 15 s signal integration period with a signal-to-noise ratio of 32. We believe this represents the lowest chemical aerosol concentration and signal integration period product ever reported for a Raman spectroscopy system. The Raman system includes (i) a 10 W, 532-nm cw laser, (ii) an aerosol flow cell, (iii) a 60x aerosol concentrator, (iv) an f/1.8 Raman spectrometer with a spectral range of 400-1400 cm^-1 and a resolution of 4 cm^-1, and (v) a low-noise CCD camera (1340 x 400 pixels). The collection efficiency of the Raman system has been determined to be 2.8%. Except for the laser cooling subsystem, the Raman system fits in a 0.61 m x 0.61 m x 0.61 m box.
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Summary

A compact Raman spectroscopy system with high sensitivity to chemical aerosols has been developed. This system has been used to detect isovanillin aerosols with mass concentration of 12 pg/cm3 in a 15 s signal integration period with a signal-to-noise ratio of 32. We believe this represents the lowest chemical aerosol...

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Sensitive detection and identification of isovanillin aerosol particles at the pg/cm^3 mass concentration level using Raman spectroscopy

Chemical aerosol detection and identification using Raman scattering

August 1, 2014
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Journal Article
Author:
Roshan L. Aggarwal
…
Published in:
J. Raman Spectrosc., Vol. 45, No. 8, August 2014, pp. 677-9.
Topic:
detection systems
R&D area:
R&D group:

Summary

Early warning of the presence of chemical agent aerosols is an important component in the defense against such agents. A Raman spectrometer has been constructed for the purpose of detecting and identifying chemical aerosols. We report the detection and identification of a low-concentration chemical aerosol in atmospheric air using 532-nm continuous wave laser Raman scattering. We have demonstrated the Raman scattering detection and identification of an aerosol of isovanillin of mass concentration of 1.8 ng/cm^3 with a signal-to-noise ratio of about 19 in 30 s for the 116-cm^-1 mode with a Raman cross section of 3.3 x 10^-28 cm^2 using 8-W double-pass laser power.
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Summary

Early warning of the presence of chemical agent aerosols is an important component in the defense against such agents. A Raman spectrometer has been constructed for the purpose of detecting and identifying chemical aerosols. We report the detection and identification of a low-concentration chemical aerosol in atmospheric air using 532-nm...

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Chemical aerosol detection and identification using Raman scattering

Rational design and optimization of plasmonic nanoarrays for surface enhanced infrared spectroscopy

May 21, 2012
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Journal Article
Author:
Vladimir Liberman
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Published in:
Opt. Express, Vol. 20, No. 11, 21 May 2012, pp. 11953-11966.
Topic:
optics
R&D area:
R&D group:

Summary

We present an approach for rational design and optimization of plasmonic arrays for ultrasensitive surface enhanced infrared absorption (SEIRA) spectroscopy of specific protein analytes. Motivated by our previous work that demonstrated sub-attomole detection of surface-bound silk fibroin [Proc. Natl. Acad. Sci. U.S.A. 106, 19227 (2009)], we introduce here a general framework that allows for the numerical optimization of metamaterial sensor designs in order to maximize the absorbance signal. A critical feature of our method is the explicit compensation for the perturbative effects of the analyte's refractive index which alters the resonance frequency and line-shape of the metamaterial response, thereby leading to spectral distortion in SEIRA signatures. As an example, we leverage our method to optimize the geometry of periodic arrays of plasmonic nanoparticles on both Si and CaF2 substrates. The optimal geometries result in a three-order of magnitude absorbance enhancement compared to an unstructured Au layer, with the CaF2 substrate offering an additional factor of three enhancement in absorbance over a traditional Si substrate. The latter improvement arises from increase of near-field intensity over the Au nanobar surface for the lower index substrate. Finally, we perform sensitivity analysis for our optimized arrays to predict the effects of fabrication imperfections. We find that
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Summary

We present an approach for rational design and optimization of plasmonic arrays for ultrasensitive surface enhanced infrared absorption (SEIRA) spectroscopy of specific protein analytes. Motivated by our previous work that demonstrated sub-attomole detection of surface-bound silk fibroin [Proc. Natl. Acad. Sci. U.S.A. 106, 19227 (2009)], we introduce here a general...

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Rational design and optimization of plasmonic nanoarrays for surface enhanced infrared spectroscopy

Angle-and polarization-dependent collective excitation of plasmonic nanoarrays for surface enhanced infrared spectroscopy

June 6, 2011
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Journal Article
Author:
Vladimir Liberman
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Published in:
Opt. Express, Vol. 19, No. 12, 6 June 2011, 11202-11212.
Topic:
optics
R&D area:
R&D group:

Summary

Our recent work has showed that diffractively coupled nanoplasmonic arrays for Fourier transform infrared (FTIR) microspectroscopy can enhance the Amide I protein vibrational stretch by up to 105 times as compared to plain substrates. In this work we consider computationally the impact of a microscope objective illumination cone on array performance. We derive an approach for computing angular- and spatially-averaged reflectance for various numerical aperture (NA) objectives. We then use this approach to show that arrays that are perfectly optimized for normal incidence undergo significant response degradation even at modest NAs, whereas arrays that are slightly detuned from the perfect grating condition at normal incidence irradiation exhibit only a slight drop in performance when analyzed with a microscope objective. Our simulation results are in good agreement with microscope measurements of experimentally optimized periodic nanoplasmonic arrays.
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Summary

Our recent work has showed that diffractively coupled nanoplasmonic arrays for Fourier transform infrared (FTIR) microspectroscopy can enhance the Amide I protein vibrational stretch by up to 105 times as compared to plain substrates. In this work we consider computationally the impact of a microscope objective illumination cone on array...

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Angle-and polarization-dependent collective excitation of plasmonic nanoarrays for surface enhanced infrared spectroscopy

Advanced trigger development

November 1, 2007
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Journal Article
Author:
Thomas H. Jeys
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Published in:
Lincoln Laboratory Journal, Vol. 17, No. 1, November 2007, pp. 29-62.
Topic:
detection systems
R&D area:
R&D group:

Summary

The deadliest form of a biological attack is aerosolized agents dispersed into the atmosphere. Early detection of aerosolized biological agents is important for defense against these agents. Because of the wide range of possible attack scenarios and attack responses, there is also a wide range of detector requirements. This article focuses on real-time, single-particle, optically based bio-agent trigger detectors--the first responder to an aerosol attack--and how to engineer these detectors to achieve optimal detection performance.
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Summary

The deadliest form of a biological attack is aerosolized agents dispersed into the atmosphere. Early detection of aerosolized biological agents is important for defense against these agents. Because of the wide range of possible attack scenarios and attack responses, there is also a wide range of detector requirements. This article...

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Advanced trigger development

Measurement of aerosol-particle trajectories using a structured laser beam

June 1, 2007
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Journal Article
Author:
William D. Herzog
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Published in:
Appl. Opt., Vol. 46, No. 16, 1 June 2007, pp. 3150-3155.
Topic:
lasers
R&D area:
R&D group:

Summary

What is believed to be a new concept for the measurement of micrometer-sized particle trajectories in an inlet air stream is introduced. The technique uses a light source and a mask to generate a spatial pattern of light within a volume in space. Particles traverse the illumination volume and elastically scatter light to a photodetector where the signal is recorded in time. The detected scattering waveform is decoded to find the particle trajectory. A design is presented for the structured laser beam, and the accuracy of the technique in determining particle position is demonstrated. It is also demonstrated that the structured laser beam can be used to measure and then correct for the spatially dependent instrument-response function of an optical-scattering-based particle-sizing system for aerosols.
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Summary

What is believed to be a new concept for the measurement of micrometer-sized particle trajectories in an inlet air stream is introduced. The technique uses a light source and a mask to generate a spatial pattern of light within a volume in space. Particles traverse the illumination volume and elastically...

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Measurement of aerosol-particle trajectories using a structured laser beam
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