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Development of adaptive liquid microlenses and microlens arrays

Published in:
SPIE Photonics West 2013: MOEMS-MEMS, 2-7 February 2013.

Summary

We report on the development of sub-millimeter size adaptive liquid microlenses and microlens arrays using two immiscible liquids to form individual lenses. Microlenses and microlens arrays having aperture diameters as small as 50 microns were fabricated on a planar quartz substrate using patterned hydrophobic/hydrophilic regions. Liquid lenses were formed by a self-assembled oil dosing process that created well-defined lenses having a high fill factor. Variable focus was achieved by controlling the lens curvature through electrowetting. Greater than 70 degrees of contact angle change was achieved with less than 20 volts, which results in a large optical power dynamic range.
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Summary

We report on the development of sub-millimeter size adaptive liquid microlenses and microlens arrays using two immiscible liquids to form individual lenses. Microlenses and microlens arrays having aperture diameters as small as 50 microns were fabricated on a planar quartz substrate using patterned hydrophobic/hydrophilic regions. Liquid lenses were formed by...

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Switchable electrowetting of droplets on dual-scale structured surfaces

Published in:
J. Vac. Sci. Technol. B, Microelectron. Process. Phenon., Vol. 30, No. 6, November 2012, 06F801.

Summary

The authors report on the development of surfaces containing artificially fabricated structures of dual nanometer and micrometer surfaces that allow an aqueous droplet to be reversibly switched by electrowetting from a Cassie state with low adhesion to a Wenzel state with high adhesion. A variety of geometries were fabricated to study parameters that affect switchable wetting-dewetting. Nanometer parallel corrugations, posts, and holes were fabricated and combined with micrometer features consisting of parallel corrugations, streets, and checkerboard patterns of varying widths and pitches. It was observed that many combinations of the dual-textured surfaces produced superhydrophobic wetting states and aqueous droplets on these surfaces could be electrically controlled to switch from a Cassie state to a Wenzel state. Reversible switching between these wetting states occurred on specific combinations of surface geometries, namely surfaces that had parallel corrugations.
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Summary

The authors report on the development of surfaces containing artificially fabricated structures of dual nanometer and micrometer surfaces that allow an aqueous droplet to be reversibly switched by electrowetting from a Cassie state with low adhesion to a Wenzel state with high adhesion. A variety of geometries were fabricated to...

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Dynamic photoacoustic spectroscopy for trace gas detection

Published in:
Appl. Phys. Lett., Vol. 101, No. 18, 29 October 2012, 184103.

Summary

We present a method of photoacoustic spectroscopy in which a laser beam tuned to an absorption feature of a gas is swept through its plume at the speed of sound. The resulting coherent addition of acoustic waves leads to an amplification of the signal without the need for a resonant chamber, thus enhancing the ability to remotely sense the gas. We demonstrate the concept using a tunable CO2 laser and SF6 gas in conjunction with a microphone. Sound pressure levels of 83 dB (relative to 20 uPa) are generated from a 15-ppm plume.
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Summary

We present a method of photoacoustic spectroscopy in which a laser beam tuned to an absorption feature of a gas is swept through its plume at the speed of sound. The resulting coherent addition of acoustic waves leads to an amplification of the signal without the need for a resonant...

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Reversible electrowetting on dual-scale-patterned corrugated microstructured surfaces

Published in:
J. of Microeletromechanical Systems, Vol. 21, No. 5, October 2012, pp. 1261-71.

Summary

The ability to reversibly switch between a hydrophobic Cassie state and a hydrophilic Wenzel state is often not possible on textured surfaces because of energy barriers which result from the geometry of the microstructure. In this paper, we report on a simple microstructure geometry that allows an aqueous droplet to be reversibly switched between these states by the application of electrowetting. We demonstrate reversible electrowetting in air on microstructured surfaces consisting of parallel corrugations and show that this geometry can be engineered to produce a Cassie state and can be electrically controlled to switch to a Wenzel wetting state having high adhesion. When the electric field was removed, we observed spontaneous dewetting along the corrugations as the droplet transitioned from the Wenzel state back to a Cassie state.
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Summary

The ability to reversibly switch between a hydrophobic Cassie state and a hydrophilic Wenzel state is often not possible on textured surfaces because of energy barriers which result from the geometry of the microstructure. In this paper, we report on a simple microstructure geometry that allows an aqueous droplet to...

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Rational design and optimization of plasmonic nanoarrays for surface enhanced infrared spectroscopy

Published in:
Opt. Express, Vol. 20, No. 11, 21 May 2012, pp. 11953-11966.

Summary

We present an approach for rational design and optimization of plasmonic arrays for ultrasensitive surface enhanced infrared absorption (SEIRA) spectroscopy of specific protein analytes. Motivated by our previous work that demonstrated sub-attomole detection of surface-bound silk fibroin [Proc. Natl. Acad. Sci. U.S.A. 106, 19227 (2009)], we introduce here a general framework that allows for the numerical optimization of metamaterial sensor designs in order to maximize the absorbance signal. A critical feature of our method is the explicit compensation for the perturbative effects of the analyte's refractive index which alters the resonance frequency and line-shape of the metamaterial response, thereby leading to spectral distortion in SEIRA signatures. As an example, we leverage our method to optimize the geometry of periodic arrays of plasmonic nanoparticles on both Si and CaF2 substrates. The optimal geometries result in a three-order of magnitude absorbance enhancement compared to an unstructured Au layer, with the CaF2 substrate offering an additional factor of three enhancement in absorbance over a traditional Si substrate. The latter improvement arises from increase of near-field intensity over the Au nanobar surface for the lower index substrate. Finally, we perform sensitivity analysis for our optimized arrays to predict the effects of fabrication imperfections. We find that
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Summary

We present an approach for rational design and optimization of plasmonic arrays for ultrasensitive surface enhanced infrared absorption (SEIRA) spectroscopy of specific protein analytes. Motivated by our previous work that demonstrated sub-attomole detection of surface-bound silk fibroin [Proc. Natl. Acad. Sci. U.S.A. 106, 19227 (2009)], we introduce here a general...

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Driven dynamics and rotary echo of a qubit tunably coupled to a harmonic oscillator

Summary

We have investigated the driven dynamics of a superconducting flux qubit that is tunably coupled to a microwave resonator. We find that the qubit experiences an oscillating field mediated by off-resonant driving of the resonator, leading to strong modifications of the qubit Rabi frequency. This opens an additional noise channel, and we find that low-frequency noise in the coupling parameter causes a reduction of the coherence time during driven evolution. The noise can be mitigated with the rotary-echo pulse sequence, which, for driven systems, is analogous to the Hahn-echo sequence.
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Summary

We have investigated the driven dynamics of a superconducting flux qubit that is tunably coupled to a microwave resonator. We find that the qubit experiences an oscillating field mediated by off-resonant driving of the resonator, leading to strong modifications of the qubit Rabi frequency. This opens an additional noise channel...

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Photonic ADC: overcoming the bottleneck of electronic jitter

Summary

Accurate conversion of wideband multi-GHz analog signals into the digital domain has long been a target of analog-to-digital converter (ADC) developers, driven by applications in radar systems, software radio, medical imaging, and communication systems. Aperture jitter has been a major bottleneck on the way towards higher speeds and better accuracy. Photonic ADCs, which perform sampling using ultra-stable optical pulse trains generated by mode-locked lasers, have been investigated for many years as a promising approach to overcome the jitter problem and bring ADC performance to new levels. This work demonstrates that the photonic approach can deliver on its promise by digitizing a 41 GHz signal with 7.0 effective bits using a photonic ADC built from discrete components. This accuracy corresponds to a timing jitter of 15 fs - a 4-5 times improvement over the performance of the best electronic ADCs which exist today. On the way towards an integrated photonic ADC, a silicon photonic chip with core photonic components was fabricated and used to digitize a 10 GHz signal with 3.5 effective bits. In these experiments, two wavelength channels were implemented, providing the overall sampling rate of 2.1 GSa/s. To show that photonic ADCs with larger channel counts are possible, a dual 20- channel silicon filter bank has been demonstrated.
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Summary

Accurate conversion of wideband multi-GHz analog signals into the digital domain has long been a target of analog-to-digital converter (ADC) developers, driven by applications in radar systems, software radio, medical imaging, and communication systems. Aperture jitter has been a major bottleneck on the way towards higher speeds and better accuracy...

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Retroreflectors for remote readout of colorimetric sensors

Published in:
Sensors and Actuators B-Chemical, Vol. 160, No. 1, 15 December 2011, pp. 1244-1249.

Summary

We have developed a remote detection system consisting of commercially available retroreflective material coated with an analyte-specific colorimetric dye. Quantitative performance modeling predicts that, given the appropriate indicator dye, a system with a 10 cm optic and eye-safe illumination should be capable of detecting small droplets of contamination at kilometer ranges. We have synthesized new colorimetric dyes specific to organophosphate contamination and, with these dyes, demonstrated detection of 1um of liquid malathion at over 150 m with less than 20 mW of laser illumination.
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Summary

We have developed a remote detection system consisting of commercially available retroreflective material coated with an analyte-specific colorimetric dye. Quantitative performance modeling predicts that, given the appropriate indicator dye, a system with a 10 cm optic and eye-safe illumination should be capable of detecting small droplets of contamination at kilometer...

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Noncontact optical detection of explosive particles via photodissociation followed by laser-induced fluorescence

Published in:
Opt. Express, Vol. 19, No. 19, 12 September 2011, pp. 18671-18677.

Summary

High-sensitivity (ng/cm2) optical detection of the explosive 2,4,6- trinitrotoluene (TNT) is demonstrated using photodissociation followed by laser-induced fluorescence (PD-LIF). Detection occurs rapidly, within 6 laser pulses (~7 ns each) at a range of 15 cm. Dropcasting is used to create calibrated samples covering a wide range of TNT concentrations; and a correspondence between fractional area covered by TNT and PD-LIF signal strength is observed. Dropcast data are compared to that of an actual fingerprint. These results demonstrate that PD-LIF could be a viable means of rapidly and remotely scanning surfaces for trace explosive residues.
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Summary

High-sensitivity (ng/cm2) optical detection of the explosive 2,4,6- trinitrotoluene (TNT) is demonstrated using photodissociation followed by laser-induced fluorescence (PD-LIF). Detection occurs rapidly, within 6 laser pulses (~7 ns each) at a range of 15 cm. Dropcasting is used to create calibrated samples covering a wide range of TNT concentrations; and...

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Angle-and polarization-dependent collective excitation of plasmonic nanoarrays for surface enhanced infrared spectroscopy

Summary

Our recent work has showed that diffractively coupled nanoplasmonic arrays for Fourier transform infrared (FTIR) microspectroscopy can enhance the Amide I protein vibrational stretch by up to 105 times as compared to plain substrates. In this work we consider computationally the impact of a microscope objective illumination cone on array performance. We derive an approach for computing angular- and spatially-averaged reflectance for various numerical aperture (NA) objectives. We then use this approach to show that arrays that are perfectly optimized for normal incidence undergo significant response degradation even at modest NAs, whereas arrays that are slightly detuned from the perfect grating condition at normal incidence irradiation exhibit only a slight drop in performance when analyzed with a microscope objective. Our simulation results are in good agreement with microscope measurements of experimentally optimized periodic nanoplasmonic arrays.
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Summary

Our recent work has showed that diffractively coupled nanoplasmonic arrays for Fourier transform infrared (FTIR) microspectroscopy can enhance the Amide I protein vibrational stretch by up to 105 times as compared to plain substrates. In this work we consider computationally the impact of a microscope objective illumination cone on array...

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